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Coordination complex
A metal salen complex is a coordination compound between a metal cation and a ligand derived from N,N′-bis(salicylidene)ethylenediamine, commonly called
Metal_salen_complex
Chemical compound
various oxidation states. For this reason salen-type compounds are used as metal deactivators. Metal salen complexes also find use as catalysts. H2salen may
Salen_ligand
cobalt(II) complex of salen ligand is the first synthetic O2 carrier. Solvated derivatives of the solid complex bind 0.5 equivalents of O2: 2 Co(salen) + O2
Transition metal dioxygen complex
Transition_metal_dioxygen_complex
Chemical compound
a salen ligand, tetradentate, meaning it binds to the central manganese metal through four bonds, one to each oxygen and nitrogen atom of the salen backbone
Jacobsen's_catalyst
Chemical compound
Salcomine is a coordination complex derived from the salen ligand and cobalt. The complex, which is planar, and a variety of its derivatives are carriers
Salcomine
Class of chemical compounds
Through Metal-Heteroatom Bonds". Organotransition Metal Chemistry. MIT Press. ISBN 978-1-891389-53-5. Cozzi, Pier Giorgio (2004). "Metal-Salen Schiff base
Metal_halides
Supermolecular coordination-based assembly methodology
trans-WLA complex was reported by the Mirkin group in 2017. In this complex, two NHC groups adopt a trans-coordination geometry around a Pd(II) metal center
Weak-Link_Approach
Chemical compound
The molecular structure of pure (metal-free) salpn, sometimes denoted H2(salpn) or salpnH2, can be described as the salen ligand with a methyl group attached
Salpn_ligand
example, heating the metal salen complex bis(salicylaldehyde)ethylenediiminecobalt(II) ("Co-salen") in air to 500 °C. The precursor Co-salen can be obtained
Cobalt_oxide_nanoparticle
American biochemist
characterization of metal salen complexes of manganese and vanadium, and nitrogen and oxygen transfer reactivity with these complexes, respectively. Chang
Christopher_Chang
Chemical reaction
is still bonded to the manganese metal. Then, the Mn–O bond breaks and the epoxide is formed. The Mn(III)-salen complex is regenerated, which can then be
Jacobsen_epoxidation
Synthetic compounds
of manganese, iron, or copper (and zinc) coordination complexes. Salen-manganese(III) complexes contain aromatic ring structures that increase the lipid
Superoxide_dismutase_mimetics
Chemical reaction
is that developed by Shaw et al. in 2014. Using a catalytic Fe(III)-(Salen) complex, Shaw and coworkers were able to access chiral cyclopentanes from an
Conia-ene_reaction
Organic compound containing the group >C=N–
Copper(II) complex of the Schiff base ligand salicylaldoxime. Salen is a common tetradentate ligand that becomes deprotonated upon complexation. Jacobsen's
Schiff_base
American chemist
Nocera. Yang's work in the Nocera lab focused on the synthesis of novel salen complexes that mimic the activity of the catalase enzyme, and exhibit epoxidation
Jenny_Y._Yang
Japanese Chemist
During this time he studied the epoxidation of alkenes catalyzed by metal-salen complexes. Miyaura joined Hokkaido University as a research associate in the
Norio_Miyaura
Chemical reaction involving a change in spin state
encountered in transition metal chemistry since many metal ions can adopt multiple spin states. For example, ferrous porphyrin complexes containing one axial
Spin-forbidden_reactions
Ligands that lack mirror symmetry but have two-fold rotational symmetry
important anticancer drug. Jacobsen's epoxidation catalyst is a complex of a C2-symmetric salen-type ligand. C2-symmetric diene ligand. Both bi- and tridentate
C2-Symmetric_ligands
magnets, such as Fe(salen)-based "anticancer nanomagnet" with proven cancer-fighting ability. However, insoluble drugs including Fe(salen) also have some
Magnetic_drug_delivery
Class of materials
Prussian blue related compounds, and charge-transfer complexes. In 2015 oxo-dimeric Fe(salen)-based magnets ("anticancer nanomagnets") in a water suspension
Molecule-based_magnets
Chemical reaction
process. Oxidative phenol couplings are often catalyzed by transition metal complexes including V, Cr, Mn, Cu, Fe, among others. Such reactions often form
Oxidative_coupling_of_phenols
American organic chemist
enantioselective alkylations with tributyltin enolates catalyzed by a Cr(salen)Cl catalyst. She also worked on the development of an enantioselective addition
Abigail_Doyle
Stabilizer added to polymeric materials
chelation to form an inactive coordination complex with the metal ion. Salen-type compounds are common. Thermal (or heat) stabilizers are used almost
Polymer_stabilizer
of a phosphasalen ligand, an iminophosphorane analog of the well-known salen ligand. The authors suggest that the strong 𝜎 and π donation to the electron
Iminophosphorane
Chemical compound
The White catalyst is a transition metal coordination complex named after the chemist by whom it was first synthesized, M. Christina White, a professor
White_catalyst
2016 video game
commander of the starship Olympus Mons, and leader of the SDF, Rear Admiral Salen Kotch (Kit Harington), and his senior commander Akeel Min Riah (Jim Pirri)
Call of Duty: Infinite Warfare
Call_of_Duty:_Infinite_Warfare
Canadian chemist
acid metal centers with chiral ligand supports to open cyclic lactones via ring-opening polymerizations. The second is the use of a chiral indium salen catalyst
Parisa_Mehrkhodavandi
Catalyst for the industrial production of plastics
bidentate ligands related to salen ligands. and DuPont. The concept of bulky bis-imine ligands was extended to iron complexes Representative catalysts feature
Post-metallocene_catalyst
Technique of oxidizing various substrates
One named reaction is the Jacobsen epoxidation, which uses manganese-salen complex as a chiral catalyst and NaOCl as the oxidant. The Sharpless epoxidation
Asymmetric catalytic oxidation
Asymmetric_catalytic_oxidation
Concept in toxicology
interaction between DNA with the carcinogenic chromium by using a Cr(V)-Salen complex at the specific oxidation state. The interaction was specific to the
Genotoxicity
Chemical compound
water); the reaction was perceived to proceed via a complexation of a pair of carpacins to the Pd(II) metal via their phenolic anions (as shown in scheme,
Carpanone
Ligand which binds 4 donor atoms in a coordination complex
alkali metals in ethers". Journal of the Chemical Society: 3767. doi:10.1039/JR9590003767. McAuliffe, C. A. (1973). Transition Metal Complexes of Phosphorus
Tetradentate_ligand
American scientist (1927–2008)
Kochi, J. K. (1986). "Epoxidation of olefins with cationic (salen)manganese(III) complexes. The modulation of catalytic activity by substituents". Journal
Jay_Kochi
Jordan, and Asher treat Salen Morrison, a clinic patient whose bizarre behavior hampers their efforts to treat her. Salen later admits that she was
List of The Good Doctor episodes
List_of_The_Good_Doctor_episodes
Chemical compound
N′-disalicylidene-1,2-propanediamine, a salen-type ligand, usually abbreviated as salpn, that is used as a metal deactivating additive in motor oils. 1
1,2-Diaminopropane
Stadium in Santiago, Chile
Hernández hará su primer concierto en el Estadio Nacional: revisa cuándo salen las entradas" [Myriam Hernández will perform her first concert at the Estadio
Estadio Nacional Julio Martínez Prádanos
Estadio_Nacional_Julio_Martínez_Prádanos
Class of chemical compounds
A mechanistic study of pyrophosphate detection with a "flexible" Fe-salen complex". Inorganic Chemistry Frontiers. 8 (19): 4313–4323. doi:10.1039/d1qi00209k
Pyrophosphate
Compound analogous to naturally occurring RNA and DNA
planar. Metal-complexing with DNA can occur by the formation of non-canonical base pairs from natural nucleobases with participation by metal ions and
Nucleic_acid_analogue
Romanian gymnast (born 1961)
maint: multiple names: authors list (link) Comăneci Comăneci, pp. 17–19. Salen, Erika (September 26, 2024). "Made In Romania - Nadia Comăneci- Romania's
Nadia_Comăneci
Class of chemical compounds
known, including amino acid salts, and also complexes from iron group, rare-earth, and actinide metals. Complexes are not usually identified as nitrate chlorides
Nitrate_chlorides
Chemical compound
toluene at approx. 14 bar CO pressure and 55 °C in the presence of a salen complex within 24 h with inversion of the configuration in 94% yield to optically
Β-Butyrolactone
catalyst (RuCl2(PCy3)(CH(C6H4)OiPr)) Jacobsen's catalyst (derivative of Mn(salen)Cl) Jones reagent (CrO3 / H2SO4(aq) / Me2CO) Jordan's cation ((Cp)2Zr(Me)(THF)+)
List of inorganic compounds named after people
List_of_inorganic_compounds_named_after_people
German chemist
Schulz, Emmanuelle; David, Olivier R. P. (2022-05-11). "Making Chiral Salen Complexes Work with Organocatalysts". Chemical Reviews. 122 (9): 8841–8883. doi:10
René_Peters_(chemist)
City in Västergötland, Sweden
northeast of Trollhättan. The airport provides direct routes to Stockholm and Sälen which are operated by NyxAir formerly Västflyg. The nearest international
Trollhättan
the original on 7 March 2021. Retrieved 26 March 2021. "Christina Nilsson Salen" (in Swedish). Växjö Konserthus. Archived from the original on 11 April
List_of_concert_halls
French chemist (born 1931)
of [Gd(hfa)3Cu(salen)], [Y(hfa)3Cu(salen)], [Gd(hfa)3Cu(salen)(Meim)], and [La(hfa)3(H2O)Cu(salen)], hfa=hexafluoroacetylacetonato, salen=N
Yves_Jeannin
Bears kept in captivity to harvest their bile
(2): G334–41. doi:10.1152/ajpgi.00406.2015. PMID 27340129. Tint, G. S.; Salen, G.; Colalillo, A.; Graber, D.; Verga, D.; Speck, J.; Shefer, S. (September
Bile_bear
Method of separating enantiomers in a racemic mixture by reaction rate
racemization occurs with loss of the acetate, forming a cationic complex with the transition metal center, as shown below. Palladium has been shown to facilitate
Kinetic_resolution
Game with physically enacted role-play
a traditional 'tabletop' roleplaying game and improvisational theatre." Salen, Katie; Zimmerman, Eric (2003). Rules of Play: Game Design Fundamentals
Live_action_role-playing_game
Chemical compound
stabilized by N,N,O,O coordination from a salen ligand. Jacobson's catalyst and related Mn(III)–Cl complexes react with O-atom transfer reagents to form
Manganese(III)_chloride
Organic compound or functional group containing a C=N bond
the salen ligands. Metal-catalyzed reactions of imines proceed through such complexes. In classical coordination complexes, imines bind metals through
Imine
Organic compound with a –C≡N functional group
Addition of Trimethylsilyl Cyanide to Aldehydes Catalyzed by Chiral (Salen)Titanium Complexes", Journal of the American Chemical Society, 121 (16): 3968–3973
Nitrile
Video game genre
within a narrative framework, generally with few or no action elements. Salen & Zimmerman 2004, p. 385. Todd, Deborah (23 February 2007). "The Hat Trick
Adventure_game
International airport in Greater Manchester, England
Whistleblower programme revealed security failures at the airport, including faulty metal detectors and a lack of regular random baggage checks. In 2005, police used
Manchester_Airport
to create functional internal spaces. Unlike extended networks such as metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), these
Organic_molecular_cages
Chemical reaction(s) which favor one chiral isomer over another
ligands", are effective in a wide range of reactions; examples include BINOL, Salen, and BOX. Most catalysts are effective for only one type of asymmetric reaction
Enantioselective_synthesis
Organic chemist
using yttrium- and lanthanide- salen complexes. The RajanBabu group has also developed water-soluble Rhodium(I) complexes, allowing for reactions to be
T._V._Rajan_Babu
Process of developing a video game
ISBN 0-321-20467-0. Salen, Katie; Zimmerman, Eric (2005). The Game Design Reader: A Rules of Play Anthology. The MIT Press. ISBN 0-262-19536-4. Salen, Katie; Zimmerman
Video_game_development
Protein-coding gene in the species Homo sapiens
Stalenhoef AF, Mietinnen T, Bjorkhem I, Bruckert E, Pandya A, Brewer HB, Salen G, Dean M, Srivastava A, Patel SB (Aug 2001). "Two genes that map to the
ABCG5
State of Mexico
2010. Jorge Escalante comunidad estadounidense. (September 17, 2001). "Salen estadounidenses al 'grito' en San Miguel" [Americans leave the "Grito" in
Guanajuato
Chemical reaction
(java required). In another version of this reaction the ligand is based on salen and Lewis acid DIBAL is added: The Simmons–Smith reaction can be used to
Simmons–Smith_reaction
Organic compounds containing the azide (N3) functional group
"Highly Enantioselective Ring Opening of Epoxides Catalyzed by (salen)Cr(III) Complexes". Journal of the American Chemical Society. 117 (21): 5897–5898
Organic_azide
List of tornadoes in Europe and surrounding regions in 2025
Region Country Start coord. Time (UTC) Path length Max. width IF1.5 W of Sälen Dalarna Sweden 61°09′22″N 12°44′57″E / 61.1560°N 12.7491°E / 61.1560;
List of European tornadoes in 2025
List_of_European_tornadoes_in_2025
Norse legendary saga
kommer); "The Fighting of the Drunkards in the Hall" (De drucknas strid i salen); and "The Power of the Harp" (Harpans makt). In modern science fiction
Norna-Gests_þáttr
City in Hidalgo, Mexico
Gutiérrez Pérez, Julieta (November 28, 2022). "Apagón radiofónico en Hidalgo; salen del aire 10 estaciones". La Silla Rota (in Spanish). Retrieved January 14
Actopan,_Hidalgo
Analytical methodology in spectroscopy
(2005). "Mechanistic Insights into the Oxidation of Veratryl Alcohol with Co(salen) and Oxygen in Aqueous Media: An in-situ Spectroscopic Study". European
Operando_spectroscopy
Autonomous community of Spain
hojas de acanto, visibles cinco, interpolado de perlas y de cuyas hojas salen sendas diademas sumadas de perlas, que convergen en un mundo de azur o azul
Castilla–La_Mancha
Chemical reaction
5-Diaminobicyclo[2.2.2]octane, a New Scaffold for Asymmetric Catalysis via Salen−Metal Complexes". Org. Lett. 13 (9): 2488–91. doi:10.1021/ol2007378. PMID 21462988
Diels–Alder_reaction
Indian inorganic chemist (born 1946)
racemic secondary alcohols catalyzed by resin supported sulfonato-Mn (salen) complex in water". Journal of Molecular Catalysis A: Chemical. 274 (1–2): 11–15
B._M._Choudary
carbonate)s via Copolymerization of CO2 with Glycidyl Ethers Using a Cobalt Salen Catalyst and Study of a Thermally Stable Solid Polymer Electrolyte". ACS
Mark_W._Grinstaff
Protein-coding gene in the species Homo sapiens
1016/S0022-2275(20)30155-3. PMID 11893785. Lu K, Lee MH, Yu H, Zhou Y, Sandell SA, Salen G, et al. (April 2002). "Molecular cloning, genomic organization, genetic
ABCG8
Mammalian protein found in Homo sapiens
PMID 12485946. S2CID 42133087. Dussault I, Yoo HD, Lin M, Wang E, Fan M, Batta AK, Salen G, Erickson SK, Forman BM (February 2003). "Identification of an endogenous
Pregnane_X_receptor
Retrieved 9 March 2014. "Suspenden indefinidamente rutas de Metrobús que salen desde Plaza Altamira". La Patilla. 9 March 2014. Archived from the original
Timeline of the 2014 Venezuelan protests
Timeline_of_the_2014_Venezuelan_protests
METAL SALEN-COMPLEX
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METAL SALEN-COMPLEX
METAL SALEN-COMPLEX
METAL SALEN-COMPLEX
METAL SALEN-COMPLEX
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METAL SALEN-COMPLEX