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Chemical compound
Trimethylsilane is the organosilicon compound with the formula (CH3)3SiH. It is a colorless gas. It is a trialkylsilane. The Si-H bond is reactive. Being
Trimethylsilane
Chemical compound
Trimethylsilyldiazomethane Names IUPAC name (Diazomethyl)trimethylsilane Other names Trimethylsilyldiazomethane Diazo(trimethylsilyl)methane Identifiers
Trimethylsilyldiazomethane
Chemical compound
energy estimated at 84 kcal/mol. For comparison, the Si-H bond in trimethylsilane is 94 kcal/mol. With such a weak bond, the compound is used as a reagent
Tris(trimethylsilyl)silane
Chemical compound
handling provides a practical advantage over the more traditional trimethylsilane reagent. It can also be used for silyl transfer reactions to convert
Trimethylsilyl_formate
Chemical compound
January 2022. Hamann, Lawrence G.; Jones, Todd K. (2001). "(Chloromethyl)trimethylsilane". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X
(Trimethylsilyl)methyl chloride
(Trimethylsilyl)methyl_chloride
Chemical compound
Tsai, Yeun-Min; Szczepanski, Steven W. (1988). "(1-Oxo-2-Propenyl)Trimethylsilane". Organic Syntheses. 66: 14. doi:10.15227/orgsyn.066.0014. ISSN 2333-3553
Tert-Butyllithium
Fe(C5H8)(CO)3 Seyferth, Dietmar; Pornet, Jacques (1980). "(2,4-Pentadienyl)trimethylsilane: A useful pentadienylation reagent". The Journal of Organic Chemistry
Pentadienyl
Chemical compound
Bis(trimethylsilyl)peroxide Names Preferred IUPAC name Peroxybis(trimethylsilane) Identifiers CAS Number 5796-98-5 Y 3D model (JSmol) Interactive image
Bis(trimethylsilyl)peroxide
Waterproof grease made by combining a silicone oil with a thickener
polydimethylsiloxane display 1H and 13C chemical shifts similar to trimethylsilane (TMS), the reference compound for those forms of NMR spectroscopy.
Silicone_grease
Organosilicon compound
Allyltrimethylsilane Names Other names allyl trimethylsilane Identifiers CAS Number 762-72-1 Y 3D model (JSmol) Interactive image ChemSpider 63007 ECHA
Allyltrimethylsilane
Chemical compound
silacyclobutane, 1,1-dimethyl-1-silacyclobutane. Starting from (3-bromopropyl)trimethylsilane, they formed a disiloxane intermediate and subsequently generated a
Silacyclobutane
Chemical compound
Names Preferred IUPAC name {[(3E)-4-Methoxybuta-1,3-dien-2-yl]oxy}trimethylsilane Other names Kitahara diene trans-1-Methoxy-3-trimethylsilyloxy-buta-1
Danishefsky's_diene
Hydrocarbon compound (CH3–CH=CH–CH=CH2)
1c00004. Seyferth, Dietmar; Pornet, Jacques (1980). "(2,4-Pentadienyl)trimethylsilane: A useful pentadienylation reagent". The Journal of Organic Chemistry
Piperylene
Chemical compound
compounds Related compounds Dichloromethylsilane, Trichlorosilane, Trimethylsilane Except where otherwise noted, data are given for materials in their
Chlorodimethylsilane
Chemical compound
prepared via the hydrogenation of gallium trichloride, GaCl3, with trimethylsilane, Me3SiH. This step was followed by a further reduction with Li[GaH4]
Digallane
Chemical compound
reacts with vinyltrimethylsilane to form (3,3-difluoro-1,3-diiodopropyl)trimethylsilane. The compound forms pale yellow liquid that decomposes slowly at room
Difluorodiiodomethane
Chemical compound
flammable colorless gas. It is used in chemical vapor deposition. Trimethylsilane Gas Encyclopaedia Archived 2012-07-08 at the Wayback Machine, Air Liquide
Dimethylsilane
Chemical compound
Related compounds Related compounds Ethane Disilane Dimethylsilane Trimethylsilane Tetramethylsilane Except where otherwise noted, data are given for
Methylsilane
converted into the diol by a hydrolysis step. With both the acetyl trimethylsilane and propiophenone as reactants, the diol is obtained as a pure diastereoisomer
Aldol–Tishchenko_reaction
Chemical compound
was demonstrated by conducting the dechlorination in the presence of trimethylsilane: the trapped product being pentamethyldisilane: Si(CH3)2 + HSi(CH3)3
Silylene
2524-02-9 Perfluoro-2-methoxypropionylfluoride CF3OCF(CF3)C(O)F 5-8 232 Trimethylsilane (CH3)3SiH 6.7 −153.9 74 993-07-7 Carbon suboxide OCCCO 6.8 −111.3 68
List_of_gases
hydrobromic acid to give (2-bromopropyl)trimethylsilane. Six years later, the generation of (2-iodoethyl)trimethylsilane from vinylsilane and HI was observed
Electrophilic substitution of unsaturated silanes
Electrophilic_substitution_of_unsaturated_silanes
Study of chemical compounds containing fluorine-carbon bonds
deliver perfluoroalkyl and perfluoroaryl groups. (Trifluoromethyl)trimethylsilane, CF3Si(CH3)3, is used as a source of the trifluoromethyl group, for
Organofluorine_chemistry
Chemical compound
Bis(trimethylsilyl)acetylene Names Preferred IUPAC name Ethynediylbis(trimethylsilane) Other names BTMSA Identifiers CAS Number 14630-40-1 Y 3D model (JSmol)
Bis(trimethylsilyl)acetylene
Chemical used to detect unstable compounds
inference is supported by conducting the dechlorination in the presence of trimethylsilane, the trapped product being pentamethyldisilane: Si(CH3)2 + HSi(CH3)3
Chemical_trap
undergoes P3 transfer to yield HCP3. The use of bromodichloromethyl trimethylsilane instead of bromodichloromethane in this process yields trimethylsilyl
Pnictogen-substituted tetrahedranes
Pnictogen-substituted_tetrahedranes
Chemical compound
halides/pseudohalides with alkyl an aryl amines. conversion of aryl bromides into the trimethylsilanes, a functional group in many organic compounds including the fungicide
Palladium(II)_acetate
Chemical compound
Tris(trimethylsilyl)methane Names Preferred IUPAC name Methanetriyltris(trimethylsilane) Identifiers CAS Number 1068-69-5 3D model (JSmol) Interactive image
Tris(trimethylsilyl)methane
Molecular compound with applications in ceramics
oligomers. The T8 cluster was also synthesized by the reaction of trimethylsilane. The Si-H groups are amenable to hydrosilylation. Some high molecular
Silsesquioxane
Chemical compound
TMS2Hg → (CH3)3Si-Si(CH3)3 + Hg Reaction with hydrogen chloride gives trimethylsilane and trimethylsilyl chloride: TMS2Hg + HCl → TMSH + TMSCl + Hg Wiberg
Bis(trimethylsilyl)mercury
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