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Metabolic pathway
yielding propionyl-CoA. In the endoplasmic reticulum to break down phytosphingosine, which cannot undergo beta-oxidation due to its 4-hydroxy group, into
Alpha_oxidation
Chemical compound
Phytosphingosine is a sphingoid base, a fundamental building block of more complex sphingolipids. It is abundant in plants and fungi and present in animals
Phytosphingosine
Family of chemical compounds
in both yeast and mammals. These compounds, specifically known as phytosphingosine and dihydrosphingosine (also known as sphinganine, although this term
Sphingolipid
Class of enzymes
sphinganine + NADPH + H+ + O2 ⇌ {\displaystyle \rightleftharpoons } phytosphingosine + NADP+ + H2O Sphinganine C4-monooxygenase is involved in the biosynthesis
Sphinganine_C4-monooxygenase
Medical condition
S2CID 37451614. Kitamura, T; Seki, N; Kihara, A (28 March 2017). "Phytosphingosine degradation pathway includes fatty acid α-oxidation reactions in the
Sjögren–Larsson_syndrome
the endoplasmic reticulum, HACL2 (gene). This one participates in phytosphingosine degradation. Both the baker's yeast and the fission yeast have a Pxp1
2-hydroxyacyl-CoA_lyase
Chemical compound
Related compounds Related sphingolipids Sulfatide Ceramide Sphingosine Phytosphingosine Sphingosine-1-phosphate Related compounds Safingol Except where otherwise
Sphinganine
Protein-coding gene in the species Homo sapiens
sphingosine biosynthetic process sphingolipid biosynthetic process phytosphingosine biosynthetic process ceramide metabolic process positive regulation
ACER3
Protein-coding gene in the species Homo sapiens
S2CID 32001972. Candelore MR, Wright MJ, Tota LM, et al. (2002). "Phytosphingosine 1-phosphate: a high affinity ligand for the S1P(4)/Edg-6 receptor"
S1PR4
Protein-coding gene in the species Homo sapiens
corresponding aldehyde, heptadecanal or pentadecanal. It is involved in phytosphingosine degradation. There is no specific Enzyme Commission number for this
HACL2
American biochemist, and agronomist
"Biochemistry of the sphingolipides. X. Phytoglycolipide, a complex phytosphingosine-containing lipide from plant seeds". Journal of the American Oil Chemists'
Evelyn_J._Weber
American biochemist (1910–2007)
synthesis of sphingosine. Carter, H. E., and C. B. Hirschberg. 1968. Phytosphingosines and branched sphingosines in kidney. Biochemistry. 7: 2296–2300. Carter
H._E._Carter
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