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Chemical compound
Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula POCl3. It hydrolyses in moist air releasing phosphoric
Phosphoryl_chloride
Inorganic compound (SOCl2)
oxychloride (phosphoryl chloride), which resembles thionyl chloride in many of its reactions. They may be separated by distillation, since thionyl chloride boils
Thionyl_chloride
Group consisting of phosphorus and oxygen
trivalent phosphoryl group are phosphoryl chloride (O=P(−Cl)3), methylphosphonyl dichloride (O=P(−CH3)(−Cl)2) and phosphoramide (O=P(−NH2)3). A phosphoryl group
Phosphoryl_group
Chemical compound
and freezes at −96.4. Alternate names are difluorophosphoryl chloride or phosphoryl chloride difluoride. The critical temperature of POF2Cl is 150.6°C at
Phosphoryl chloride difluoride
Phosphoryl_chloride_difluoride
Chemical compound
Yonezo (1971). "Molecular structures of phosphoryl fluoride, phosphoryl chloride, and thiophosphoryl chloride studied by gas electron diffraction". Inorganic
Thiophosphoryl_chloride
Chemical data page
This page provides supplementary chemical data on phosphoryl chloride. Aldrich MSDS Fisher MSDS Deprecated link at archive.today (archived January 25
Phosphoryl chloride (data page)
Phosphoryl_chloride_(data_page)
Chemical compound
The tendency of phosphoryl fluoride toward disproportionation into those ions is not, of course, paralleled by the chloride. "Phosphoryl fluoride". Cavell
Phosphoryl_fluoride
Organic compound (CH3COCl)
chemist Charles Gerhardt by treating potassium acetate with phosphoryl chloride. Acetyl chloride is produced in the laboratory by the reaction of acetic acid
Acetyl_chloride
Chemical compound
CH3Cl + HCl Pyrophosphoryl chloride is proposed as an intermediate in the chlorination of alcohols by phosphoryl chloride. It is also a reagent for Vilsmeier-Haack
Pyrophosphoryl_chloride
Chemical compound
reagents: chloroacetic acid and catechol react in the presence of phosphoryl chloride to yield chloroacetylcatechol. After purification, chloroacetylcatechol
Adrenochrome
Chemical compound
Phosphoryl bromide, also known as phosphorus oxybromide, is an inorganic compound with the formula POBr3. Phosphoryl bromide is prepared by the reaction
Phosphoryl_bromide
Type of organic reaction
in refluxing acidic conditions and requires a dehydrating agent. Phosphoryl chloride (POCl3) is widely used and cited for this purpose. Additionally,
Bischler–Napieralski_reaction
Chemical compound
chemist Pierre Louis Dulong. Phosphorus halides Phosphorus trichloride Phosphoryl chloride Phosphorus trifluorodichloride NIOSH Pocket Guide to Chemical Hazards
Phosphorus_pentachloride
Chemical compound
TaCl5 also reacts with phosphorus pentachloride and phosphoryl chloride, the former as a chloride donor and the latter serves as a ligand, binding through
Tantalum(V)_chloride
Chemical compound
can be used to produce mustard agents. Phosphorus pentachloride Phosphoryl chloride Phosphorus trifluorodichloride NIOSH Pocket Guide to Chemical Hazards
Phosphorus_trichloride
Class of chemical compounds
Triphenylphosphine oxide is an example. An inorganic phosphine oxide is phosphoryl chloride (POCl3). The parent phosphine oxide (H3PO) remains rare and obscure
Phosphine_oxides
Chemical compound
soluble in polar solvents. Phosphoramide arises from the reaction of phosphoryl chloride with ammonia. In moist air, it hydrolyzes to an ammonium salt: 2
Phosphoramide
Chemical compound
A more efficient route involves treating 2-picoline-N-oxide with phosphoryl chloride in the presence of triethylamine: CH3C5H4NO + POCl3 + Et3N → ClCH2C5H4N
2-Chloromethylpyridine
Chemical compound
is prepared industrially by the reaction of propylene oxide with phosphoryl chloride. In practise this produces a range of products, of which the
Tris(chloropropyl)_phosphate
oxychloride 10025-87-3 1000 Phosphorus trichloride 7719-12-2 1000 Phosphoryl chloride 10025-87-3 1000 Propargyl bromide 106-96-7 100 Propyl nitrate 627-3-4
Highly_hazardous_chemical
Chemical compound
versatile reagent in organic synthesis. CSI is prepared by treating cyanogen chloride with sulfur trioxide, the product being distilled directly from the reaction
Chlorosulfonyl_isocyanate
Chemical compounds with oxygen and a halogen bonded to the same atom
Examples are phosphoryl chloride POCl3 and pyrophosphoryl chloride P2O3Cl4. Sulfur forms oxohalides in oxidation state +4, such as thionyl chloride, SOCl2 and
Oxohalide
Chemical compound
pyrophosphates. It can be prepared by reaction of phosphoric acid with phosphoryl chloride: 5 H3PO4 + POCl3 → 3 H4P2O7 + 3 HCl It can also be prepared by ion
Pyrophosphoric_acid
Chemical compound
electric discharge. Another route is the reactions of phosphoryl chloride POCl3 or nitryl chloride NO2Cl with silver nitrate AgNO3 Dinitrogen pentoxide
Dinitrogen_pentoxide
Chemical compound
synthesized by heating salicylic acid with phenol in the presence of phosphoryl chloride. It also arises from heating salicylic acid: 2 HOC6H4CO2H → C6H5O2C6H4OH
Phenyl_salicylate
Atypical antipsychotic medication
begins with a dibenzothiazepinone. The lactam is first treated with phosphoryl chloride to produce a dibenzothiazepine. A nucleophilic substitution is used
Quetiapine
Chemical compound
related to urea, hence its inhibitory function. It is a derivative of phosphoryl chloride. N-(n-butyl)thiophosphoric triamide, a related urease inhibitor Gholivand
Phenyl_phosphorodiamidate
Chemical compound
succinic acid. Such dehydration can occur with the help of acetyl chloride or phosphoryl chloride, or thermally. Industrially, succinic anhydride is prepared
Succinic_anhydride
Chemical compound
with n-butanol. Tributyl phosphate is manufactured by reaction of phosphoryl chloride with n-butanol. POCl3 + 3 C4H9OH → PO(OC4H9)3 + 3 HCl Production
Tributyl_phosphate
Chemical compound
acid and deanol in a molar ratio of 4:1:1 is added dropwise to a phosphoryl chloride solution under agitation. The product is filtered from the cake and
GV_(nerve_agent)
Fungicide
isophthalonitrile or by dehydration of tetrachloroisophthaloyl amide with phosphoryl chloride. It is a white solid. It breaks down under basic conditions, but
Chlorothalonil
Chemical compound
by reaction of methacrylic acid and 1,10-decanediol [es]. Next, phosphoryl chloride is added to 10-hydroxydecy methacrylate, then, the phosphorus-chlorine
10-Methacryloyloxydecyl dihydrogen phosphate
10-Methacryloyloxydecyl_dihydrogen_phosphate
Chemical compound
below. The final dehydration step was accomplished by treatment with phosphoryl chloride/pyridine at 75 °C. This synthesis had a 75% yield, but the final
Tremetone
Chemical compound
β-phenylethylamine is acylated and cyclodehydrated by a Lewis acid, such as phosphoryl chloride or phosphorus pentoxide. The resulting 1-substituted 3,4-dihydroisoquinoline
Isoquinoline
ISBN 0911910123. Allen, C. F. H.; Byers Jr., J. R.; Humphlett, W. J. (1963). "Oleoyl chloride". Organic Syntheses; Collected Volumes, vol. 4, p. 739.; Rutenberg, M.
List_of_reagents
Organic compounds with the structure O=P(OR)3
Atherton-Todd reaction, which converts a dialkyl phosphite to a phosphoryl chloride. This can then react with an alcohol to give an organophosphate and
Organophosphate
Chemical compound
Disulfuryl chloride fluoride (pyrosulfuryl chloride fluoride) is an inorganic compound of sulfur, chlorine, fluorine, and oxygen with the chemical formula
Disulfuryl_chloride_fluoride
Chemical compound
production of flameproofing compounds. Due to the recycling problem of phosphoryl chloride, SW was adopted in step three of the DMHP process in the preparation
Methyldichlorophosphine
Chemical compound
Sulfur chloride pentafluoride is an inorganic compound with the formula SF5Cl. It exists as a colorless gas at room temperature and is highly toxic, like
Sulfur_chloride_pentafluoride
Antihypertensive medication
7-Dimethoxyquinazoline-2,4-dione [28888-44-0] (5). Halogenation with phosphoryl chloride gives 2,4-Dichloro-6,7-dimethoxyquinazoline [27631-29-4] (6). Treatment
Alfuzosin
Chemical compound
(2017). "Removal of Triphenylphosphine Oxide by Precipitation with Zinc Chloride in Polar Solvents". The Journal of Organic Chemistry. 82 (19): 9931–9936
Triphenylphosphine_oxide
Organic reaction
including phosphorus pentachloride, phosphorus pentoxide, phosphoryl chloride, thionyl chloride, phosphoric acid-acetic anhydride, polyphosphoric acid,
Robinson–Gabriel_synthesis
Intentional introduction of impurities into an intrinsic semiconductor
for doping with boron to create p-type semiconductor regions, or Phosphoryl chloride to create n-type regions, is introduced into the furnace. This creates
Doping_(semiconductor)
Chemical compound
Phosphorothioic chloride difluoride or thiophosphoryl chloride difluoride is a chemical compound with formula PSClF2. It is normally found as a gas boiling
Phosphorothioic chloride difluoride
Phosphorothioic_chloride_difluoride
Topics referred to by the same term
Clermont-Ferrand Lyon [fr], a high-speed rail project in France Phosphoryl chloride (POCl3) This disambiguation page lists articles associated with the
POCL
Chemical compound
give the hemiaminal (CF3)2C(OH)(NH2) which can be dehydrated with phosphoryl chloride to give the imine (CF3)2CNH. Nucleophiles attack occurs at the carbonyl
Hexafluoroacetone
Chemical compound
Barium chloride fluoride is an inorganic chemical compound of barium, chlorine, and fluorine. Its chemical formula is BaClF. The compound naturally occurs
Barium_chloride_fluoride
PH3 phosphine 7803–51–2 POCl3 phosphoryl chloride 10025–87–3 PbCl2 lead(II) chloride 7758–95–4 PbCl4 lead(IV) chloride 13463–30–4 PbHAsO4 lead hydrogen
Glossary_of_chemical_formulae
Drug
8-naphthyridin-2-amine [15944-33-9] (2) gives PC23343647 (3). Halogenation with phosphoryl chloride leads to PC23343652 (4). Reductino with potassium borohydride afforded
Suproclone
Chemical compound
outlined below: The halogenation of 5-fluorouracil [51-21-8] (1) with phosphoryl chloride at high temperature gave 2,4-dichloro-5-fluoropyrimidine [2927-71-1]
Fostamatinib
Chemical compound
reactions of silicon tetrafluoride with phosphorus trichloride and phosphoryl chloride". Journal of Fluorine Chemistry. 29 (4): 463–466. Bibcode:1985JFluC
Chlorotrifluorosilane
Chemical compound
Sulfuryl chloride fluoride is a chemical compound with the formula SO2ClF. It is a colorless, easily condensed gas. It is a tetrahedral molecule. Liquified
Sulfuryl_chloride_fluoride
Index of articles associated with the same name
4-chloropyridine are prepared from the corresponding pyridinols using phosphoryl chloride. Chloropyridines are important intermediates to pharmaceuticals and
Chloropyridine
Chemical compound
reaction olivetol and the essential oil of orange in the presence of phosphoryl chloride. A method for the synthesis of THC itself consists of the condensation
Olivetol
Chemical compound found in some species of mushrooms
psilocybin sample before analysis causes it to spontaneously lose its phosphoryl group and become psilocin, making it difficult to chemically discriminate
Psilocybin
Village in Illinois, United States
people. 22 of 84 trail cars derailed; dichlorodifluromethane and phosphoryl chloride were leaked. Residents were able to return the next day, after cleanup
Smithboro,_Illinois
Chemical compound
Trixylyl phosphate is prepared industrially by the reaction of phosphoryl chloride with mixed xylenols. In practise this produces a range of isomers
Trixylyl_phosphate
Reaction in Organic Chemistry
2-Chloromethylpyridine can be prepared by treating 2-picoline-N-oxide with phosphoryl chloride or triphosgene. Wikimedia Commons has media related to Boekelheide
Boekelheide_reaction
Antiviral medication
third hydroxy group to its ester. Treatment with 1,2,4-triazole and phosphoryl chloride produces a reactive intermediate in which the triazole portion can
Molnupiravir
Type of spray nozzle
manufacturing costs of solar cell, traditionally done using the batch-based phosphoryl chloride or POCl3 method, it has been shown that using ultrasonic nozzles
Ultrasonic_nozzle
Chemical data page
(1979) CH3NO2 Nitromethane 0.172(6) 16.6(6) Adams et al. (2009) POCl3 Phosphoryl chloride 1.41(20) 136(20) Mathur et al. (1976) SF6 Sulfur hexafluoride 1.03(5)
Electron_affinity_(data_page)
Modified resistant starch
sodium tripolyphosphate (STPP) and sodium trimetaphosphate (STMP), or phosphoryl chloride (POCl3). Phosphorylated cross-linked starches is a category of modified
Phosphated_distarch_phosphate
Chemical compound
oxide can be obtained by reaction between phosphoryl chloride and the Grignard reagent methylmagnesium chloride. POCl3 + 3 CH3MgCl → (CH3)3PO + 3 MgCl2
Trimethylphosphine_oxide
((CH3)3Si−O−P(=O)F2) reacts with metal chlorides to give difluorophosphates. The anhydride of difluorophosphoric acid (HPO2F2), phosphoryl difluoride oxide (P2O3F4)
Difluorophosphate
Chemical compound
PEP can be prepared from the monomer (in this case estradiol) and phosphoryl chloride. The latter reacts with both the phenolic hydroxyl group in position
Polyestradiol_phosphate
Chemical compound
formation using hydrazine, giving a pyrazidinone. Treatment of this with phosphoryl chloride converts it to the required chloro derivative. Close analogues of
Minaprine
Chemical compound
acetylcholinesterase inhibitor. Ethoprop can be synthesised by reacting phosphoryl chloride with two equivalents of n-propylmercaptan and one equivalent of sodium
Ethoprophos
Chemical compound
originally prepared by the chlorination of 2-hydroxypyridine with phosphoryl chloride. 2-Chloropyridine undergoes substitution at the C-Cl bond. Some reactions
2-Chloropyridine
Chemical compound
acids suggest that the phosphorus atom is at least as electrophilic as in phosphoryl fluoride. Autodecomposition from heat gives phosphorus fluorides, sulfur
Thiophosphoryl_fluoride
Chemical compound
delayed neurotoxicity and paralysis due to acute exposure to mipafox. Phosphoryl chloride is first reacted with isopropylamine. The resulting product is then
Mipafox
Chemical compound
adding the salt of 3-amino-5-phenyl-1,2,4-triazole to a solution of phosphoryl chloride. Subsequently, gaseous dimethylamine is introduced into the reaction
Triamiphos
Sodium and calcium channel blocker
-hydroxy-2-methylpyrimidine [178430-09-6] (5). Halogenation with phosphoryl chloride led to 4-chloro-6-(4-fluorophenyl)-2-methylpyrimidine [178430-13-2]
Enecadin
Chemical compound
hydrogen chloride to form H3PO3 and phosphorus trichloride. P4O6 + 6 HCl → 2 H3PO3 + 2 PCl3 With chlorine or bromine it forms the corresponding phosphoryl halide
Phosphorus_trioxide
Derivative of tetrahydrocannabinol
prodrug for psilocin. THC phosphate ester is made by reacting THC with phosphoryl chloride using pyridine as a solvent, following by quenching with water to
THC-O-phosphate
Chemical compound used as an intermediate to antimalarial drugs
in the 4-position is converted into the second chloro group using phosphoryl chloride. The availability of 4,7-dichloroquinoline allowed alternative structural
4,7-Dichloroquinoline
Class of elements
example, thallium(I) chloride and bromide are light-sensitive, and thallium(I) fluoride is more soluble in water than the chloride and bromide. Thallium(I)
Thallium_halides
Chemical compounds containing phosphorus bound to a halogen
reaction with organic peroxides or ozone: they are sometimes referred to as phosphoryl halides. The thiohalides, also known as thiophosphoryl halides may be
Phosphorus_halide
Reaction in organic chemistry
1007/128_073. ISBN 978-3-540-68097-0. Stamos, Ioannis K. (1986). "Arylation of α-phosphoryl sulfides via their pummerer rearrangement intermediates generated from
Pummerer_rearrangement
Chemical compound
Bramanti V, Amenta F (December 2013). "Choline alphoscerate (alpha-glyceryl-phosphoryl-choline) an old choline- containing phospholipid with a still interesting
Glycerophosphorylcholine
Reactive class of chemicals
in situ. Dehydrohalogenation of butenoyl chloride produces 1,3-butadienal, with substituted acyl chlorides likewise producing substituted vinylketenes;
Vinylketenes
Enzyme
domains. Phosphoryl groups are transferred during PEPCK action, which is likely facilitated by the eclipsed conformation of the phosphoryl groups when
Phosphoenolpyruvate carboxykinase
Phosphoenolpyruvate_carboxykinase
are in wide use or of significant historical interests. Actinium(III) chloride – AcCl3 Actinium(III) fluoride – AcF3 Actinium(III) oxide – Ac2O3 Actinium(III)
List_of_inorganic_compounds
Chemical compound
PC23311140 (3). The reaction of this a mixture of formamide and phosphoryl chloride gave the ring. The addition of perchloric acid led to 1-(4-Chlorophenyl)[1
Trazium
Inorganic chemical compound
Strontium fluorochloride or strontium fluoride chloride is an inorganic compound of strontium, fluorine, and chlorine with the chemical formula SrFCl.
Strontium_fluorochloride
Chemical compound
vivo and in vitro inhibition of cholinesterase by methyl-1 (S methyl phosphoryl-3) imidazolium (MSPI), a model of an "instantly" aged phosphorylated enzyme"
MSPI_(nerve_agent)
Chemical compound
(tripitramine) Tropacine Tropatepine Tropicamide Tropine benzilate Trospium chloride Typical antipsychotics (e.g., chlorpromazine, chlorprothixene, cyamemazine
Phosphorylcholine
Chemical compound
to hydrolysis. DCFP can be produced by reaction of cyclohexanol with phosphoryl dichloride fluoride. Diisopropyl phosphorofluoridate (DFP) BERRY, WK (October
Dicyclohexyl phosphorofluoridate
Dicyclohexyl_phosphorofluoridate
several hours Trifluoromethylsulfinyl chloride CF3S(O)Cl Nitrosyl cyanide ?−20° blue-green gas 4343-68-4 Thiazyl chloride NSCl greenish yellow gas; trimerises
List_of_gases
Chemical compound
Phosphorus monoxide Names Other names oxophosphanyl; oxidophosphorus(.); Phosphoryl Identifiers CAS Number 14452-66-5 3D model (JSmol) Interactive image ChEBI
Phosphorus_monoxide
Chemical compound
(help) John M. Read, Yu-Pu Wang, Rick L. Danheiser (2015). "Synthesis of Phosphoryl Ynamides by Copper-Catalyzed Alkynylation of Phosphoramidates. Preparation
Diethyl_phosphite
Class of organophosphates; classified as weapons of mass destruction
as does atropine, pralidoxime chloride reactivates the poisoned enzyme (acetylcholinesterase) by scavenging the phosphoryl group attached on the functional
Nerve_agent
Sulfonyl group organic reaction
ISBN 9780470147306. Wadsworth, W. S. (1977). "Synthetic Applications of Phosphoryl-Stabilized Anions". Org. React. 25: 73–253. doi:10.1002/0471264180.or025
Reductive_desulfonylation
Property of ions and molecules
Ethylene 680 Phosphorus trifluoride 697 Water 697 Carbon disulfide 699 Phosphoryl trifluoride 702 2,4-Dicarba-closo-heptaborane(7) 703 Hydrogen sulfide
Proton_affinity
Chemical compound
IUPAC name 5'-O-[hydroxy({hydroxy[2-(trimethylammonio)ethoxy] phosphoryl}oxy)phosphoryl]cytidine CAS Number 987-78-0 Y PubChem CID 11583971 ChemSpider
Citicoline
Chemical compound
Chlorotrifluoromethane Monochlorotrifluoromethane Trifluorochloromethane Trifluoromethyl chloride Trifluoromonochlorocarbon Arcton 3 Freon 13 Genetron 13 R-13 CFC 13 UN
Chlorotrifluoromethane
Class of Chemical Compounds
make these salts include treating a metal chloride with anhydrous fluorosulfuric acid, releasing hydrogen chloride gas. Double decomposition methods utilising
Fluorosulfates
Chemical compound
[page needed] Thionyl fluoride can be produced by the reaction of thionyl chloride with fluoride sources such as antimony trifluoride. 3 SOCl2 + 2 SbF3 →
Thionyl_fluoride
Chemical compound
They are mainly of interest by researchers, unlike the related iron(III) chloride. Anhydrous iron(III) fluoride is white, whereas the hydrated forms are
Iron(III)_fluoride
Chemical compound
through the skin. In contact with water, it is expected to give off hydrogen chloride and dimethylamidophosphoric acid vapors. First synthesis of the substance
Dimethylamidophosphoric dichloride
Dimethylamidophosphoric_dichloride
Organic compound with at least one covalent carbon–phosphorus bond
produced annually by the reaction of phosphorus pentasulfide with alcohols. Phosphoryl thioates are thermodynamically much stabler than thiophosphates, which
Organophosphorus_chemistry
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