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Chemical compound
Phosphanides are chemicals containing the [PH2]− anion. This is also known as the phosphino anion or phosphido ligand. The IUPAC name can also be dihydridophosphate(1−)
Phosphanide
Chemical compound
condenses to a colorless liquid. It can be produced by methylation of phosphanide salts: KPH2 + MeI → MePH2 + KI The compound exhibits the properties characteristic
Methylphosphine
Anion derived from deprotonation of ammonia
Ammonia Structure Molecular shape Bent Related compounds Other anions Phosphanide Arsinide Imide Nitride Nitridohydride Related isoelectronic water, fluoronium
Azanide
Chemical compound
Structures of Sterically Congested Sodium and Cesium Silyl(fluorosilyl)phosphanide Aggregates and Structural Characterization of the Trimeric Sodium
Sodium bis(trimethylsilyl)amide
Sodium_bis(trimethylsilyl)amide
Chemical compound hydrogen phosphide
exchange proceeds via a phosphonium (PH+4) ion in acidic solutions and via phosphanide (PH−2) at high pH, with equilibrium constants Kb = 4×10−28 and Ka = 41
Phosphine
Ion containing two or more atoms
phosphate HPO2−4 Hydrogen peroxymonophosphate HPO2−5 Protonated twice Phosphanide H2P− Phosphinate or hypophosphite H2PO−2 Hydrogen phosphite H2PO−3 Dihydrogen
Polyatomic_ion
Chemical compound
compounds Related compounds Arsanylium AsH+2 Arsine AsH3 Azanide NH−2 Phosphanide PH−2 Except where otherwise noted, data are given for materials in their
Arsinide
selenium analog of hydroxide Azanide, a nitrogen analog of hydroxide Phosphanide, a phosphorus analog of hydroxide and azanide Arsanide, an arsenic analog
Alkali_hydroxide
Chemical compound
through sequential phosphanide/phosphine displacement of 1,3-alkyl dihalides or sulfonate esters (OTf, OTs, OMs, etc.). The phosphanide source is commonly
Phosphetane
phosphido is often a bridging ligand. The -PH2 ion or ligand is also called phosphanide or phosphido ligand. One can generate transition-metal phosphido complexes
Transition metal phosphido complexes
Transition_metal_phosphido_complexes
Topics referred to by the same term
phph PH2, a postcode in Perth, Scotland, see PH postcode area PH2− the phosphanide ion in inorganic chemistry -PH2 the phosphanyl group in organic chemistry
Ph2
Group of chemicals
Structures of Sterically Congested Sodium and Cesium Silyl(fluorosilyl)phosphanide Aggregates and Structural Characterization of the Trimeric Sodium
Metal bis(trimethylsilyl)amides
Metal_bis(trimethylsilyl)amides
Chemical compound
structure of potassium phosphide (K3P) Names Other names Tripotassium;phosphanide Tripotassium;phosphorus(3-) Tripotassium phosphide Identifiers CAS Number
Potassium_phosphide
Class of compounds
(2010-05-17). "Germanium(II) and Tin(II) Complexes of a Sterically Demanding Phosphanide Ligand". Inorganic Chemistry. 49 (10): 4698–4707. doi:10.1021/ic1003534
Diphosphagermylene
the scheme on the left, it is also possible to use pre-formed lithium phosphanides Ar'P(H)Li as both a phosphorus source and a base. However, the latter
Phosphasilene
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