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Organic chemical reaction
The Julia olefination (also known as the Julia–Lythgoe olefination) is the chemical reaction used in organic chemistry of phenyl sulfones (1) with aldehydes
Julia_olefination
French chemist (1922–2010)
discovered the Julia olefination reaction in 1973. Julia was born in 1922 in Paris as son of the renowned mathematician Gaston Julia. Julia studied physics
Marc_Julia
Sulfonyl group organic reaction
sulfones afford either the corresponding alkanes or olefins (the Julia olefination). Reductive desulfonylation is typically accomplished with active
Reductive_desulfonylation
French mathematician (1893–1978)
1978, Julia died in Paris at the age of 85. Julia was also father to Marc Julia, the French organic chemist who invented the Julia olefination. Julia collaborated
Gaston_Julia
Organosulfur compound of the form >S(=O)2
more slowly than chloride. In the Ramberg–Bäcklund reaction and the Julia olefination, sulfones eliminate sulfur dioxide to form an alkene. Sulfones are
Sulfone
reaction Jones oxidation Jordan–Ullmann–Goldberg synthesis Julia olefination, Julia–Lythgoe olefination Kabachnik–Fields reaction Kharasch–Sosnovsky reaction
List_of_organic_reactions
Chemical compound
oxidized to the sulfone. This sequence sets the stage for the Modified Julia olefination. Oxidation gives mercaptobenzothiazole disulfide. This disulfide reacts
Mercaptobenzothiazole
Chemical compound
The second elimination reaction takes place with sodium amalgam in Julia olefination style. Wagaman, Michael W.; Bellmann, Erika; Cucullu, Michèle; Grubbs
Barrelene
Hydrocarbon compound containing one or more C=C bonds
another alternative is the Julia olefination, which uses the carbanion generated from a phenyl sulfone. The Takai olefination based on an organochromium
Alkene
Chemical coupling reaction
The Wittig reaction or Wittig olefination is a chemical reaction of an aldehyde or ketone with a triphenyl phosphonium ylide called a Wittig reagent.
Wittig_reaction
British organic chemist
Early work with Basil Lythgoe on the scope and stereochemistry of the Julia olefination with alpha-metallated sulphone reagents emphasised the value of this
Philip_Kocienski
French neuroscience researcher
Charrier, C., Ettouati, L., & Paris, J. (1999). New application of the Julia olefination for the synthesis of Tyr-Gly E-alkene and carba isostere pseudopeptides
Cécile_Charrier
Organometallic compound containing carbon–silicon bonds
the Brook rearrangement, the Fleming–Tamao oxidation, and the Peterson olefination. The Si–C bond (1.89 Å) is significantly longer than a typical C–C bond
Organosilicon_chemistry
Chemistry technique
et al. generated extended alkane functionality by hydroformylation, olefination, and then hydrogenation. Orthogonal tandem catalysis is a "one-pot reaction
Concurrent_tandem_catalysis
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