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elimination. Multiple reviews on the topic of homoenolates and their reactivity have been published. Homoenolates are typically derived from the ring-opening
Homoenolates
Chemical compound
useful synthetically: cyclopropanol can be used as a synthon for the homoenolate of propanal. The chemical is also useful as a reagent to introduce a
Cyclopropanol
Chemical compound
component in cycloadditions with highly electron-deficient alkenes. Zinc homoenolates can also serve as indirect three-atom components, and undergo cyclization
Trimethylenemethane
Chemical compound
N-Heterocyclic Carbene-Catalyzed [8 + 3] Annulation of Tropone and Enals via Homoenolate Vijay Nair, Manojkumar Poonoth, Sreekumar Vellalath, Eringathodi Suresh
Tropone
Conversions of trialkyl to α-hydroxy phosphonates
Addition to unsaturated carbonyl compounds and deprotonation affords homoenolate equivalents. Silylated phosphite reagents are some of the most efficient
Abramov_reaction
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