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HEMILABILITY

• Hemilability

Chemical property

In coordination chemistry and catalysis hemilability (hemi - half, lability - a susceptibility to change) refers to a property of many polydentate ligands

Hemilability

Hemilability

• Transition metal complexes of phosphine oxides

Class of chemical compounds

investigation of mixed phosphine-phosphine oxide ligands, which exhibit hemilability. Typical phosphine-phosphine oxide ligands are Ph2P(CH2)nP(O)Ph2 (Ph

Transition metal complexes of phosphine oxides



Transition_metal_complexes_of_phosphine_oxides

• Pierre Braunstein

French chemist

metals », Chem. Soc. Rev., 2011, 40, p. 2741-2760 P. Braunstein, F. Naud « Hemilability of hybrid ligands and the coordination chemistry of oxazoline-based system »

Pierre Braunstein



Pierre_Braunstein

• Weak-Link Approach

Supermolecular coordination-based assembly methodology

Plasticity of the Nickel(II) Coordination Environment in Complexes with Hemilable Phosphino-Thioether Ligands,” J. Am. Chem. Soc., 2011, 133, 3023–3033

Weak-Link Approach



Weak-Link_Approach

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HEMILABILITY

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HEMILABILITY