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Chemical compound
Decamethylferrocene or bis(pentamethylcyclopentadienyl)iron(II) is a chemical compound with formula Fe(C5(CH3)5)2 or C20H30Fe. It is a sandwich compound
Decamethylferrocene
Organometallic compound: Fe(II) sandwiched between two cyclopentadienyl rings
shift the potential in the cathodic direction (more negative). Thus, decamethylferrocene is much more easily oxidised than ferrocene and can even be oxidised
Ferrocene
Chemical compound
is -0.59 V (also in dichloromethane). Decamethylcobaltocene and decamethylferrocene have very similar structures. The additional electron occupies an
Decamethylcobaltocene
Electrode with a stable and accurate electrode potential
with ferrocene or another internal standard, such as cobaltocene or decamethylferrocene, referenced back to ferrocene is ideal for nonaqueous work. Since
Reference_electrode
German chemist (born 1944)
Isolation and structural and electronic characterization of salts of the decamethylferrocene dication. August 2016 12;353(6300):678-82 Science, Xenon as a complex
Konrad_Seppelt
Organometallic chemical compound
Masters, A. F.; Phillips, L. (1999). "The Decamethylferrocenium/Decamethylferrocene Redox Couple: A Superior Redox Standard to the Ferrocenium/Ferrocene
Rhodocene
Chemistry of iron compounds containing a carbon-to-iron chemical bond
that disfavor beta-hydride elimination. Two-electron oxidation of decamethylferrocene gives the dication [Fe(C5Me5)2]2+, which forms a carbonyl complex
Organoiron_chemistry
Chemical Compound
centroid is 2.12 Å. The minor isomer adopts a D5d geometry, the same as decamethylferrocene, with the cyclopentadienyl rings parallel to one another and the
Decamethylsilicocene
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