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ORGANOCATALYST

Organocatalysis

rate of a chemical reaction is increased by an organic catalyst. This "organocatalyst" consists of carbon, hydrogen, sulfur and other nonmetal elements found

Thiourea organocatalysis

the substrate and the (thio)urea. Unlike classical catalysts, these organocatalysts interact by non-covalent interactions, especially hydrogen bonding

Squaramide catalysis

non-stereoselective and stereoselective applications. A squaramide organocatalyst typically contains the squaramide group and a hydrogen bond donor which

Enantioselective synthesis

of carbon, hydrogen, sulfur and other non-metal elements. When the organocatalyst is chiral, then enantioselective synthesis can be achieved; for example

Mannich reaction

has a substituent at the α-position, proline and similar-amino acid organocatalysts may be used to achieve the Mannich reaction stereoselectively (in regard

Α-Halo ketone

α-halo ester with a strong base (sodium hydride), a bromine donor and an organocatalyst based on proline and quinine: In the proposed reaction mechanism the

Brucine

resolving agent in 1899, and it was the first natural product used as an organocatalyst in a reaction resulting in an enantiomeric enrichment by Marckwald,

Tris(2,4,6-trimethoxyphenyl)phosphine

organophosphine whose strong Lewis-basic properties make it useful as an organocatalyst for several types of chemical reactions. TTMPP removes the trimethylsilyl

Chiral oligoethylene glycol

Class of organocatalyst of organic chemistry field

Wieland–Miescher ketone

not isolated. An enantioselective synthesis employs L-proline as an organocatalyst: This reaction was reported in 1971 by Z. G. Hajos and D. R. Parrish